ChemTalk

Biological Macromolecules

Core Concepts

In this article, you will be able to describe the chemical composition and function of the four primary biological macromolecules: carbohydrates, lipids, proteins, and nucleic acids.

Related Topics

The Four Pillars of Biochemistry

Biochemistry refers to the study of the intersection of biology and chemistry. While biochemistry is exceedingly complex, we can divide the subject into the study of four primary biological macromolecules: carbohydrates, lipids, proteins, and nucleic acids.

Biological Macromolecules
The four pillars of biochemistry involve the study of carbohydrates, lipids, proteins, and nucleic acids.

Carbohydrates

The term carbohydrate may be decomposed into the prefix “carbo-” and the suffix “-hydrate,” implying the unison of carbon and water respectively. Thus, carbohydrates have a molecular formula of Cm(H2O)n, where m and n represent numbers. Furthermore, with some exceptions, one can generalize carbohydrates by stating they are a class of polar molecules composed of only carbon (C), hydrogen (H), and oxygen (O). The chemical structures below show the linear forms of some common carbohydrates.

Carbohydrates
A schematic representing a few common carbohydrates known as monosaccharides.

As shown above, the diverse arrangement of carbon, hydrogen, and oxygen can yield a myriad of structures, which open the door for distinct functions. The table below lists the functions of carbohydrates.

Carbohydrates
The table above represents a few characteristic functions of carbohydrates.

Lipids

While carbohydrates are often termed a class of polar molecules, lipids are a class of nonpolar molecules. Furthermore, with some exceptions, lipids only contain carbon (C), hydrogen (H), and oxygen (O). The diagrams below show the linear forms of some common lipids and their constituents.

Lipids
A schematic representing a few common lipid elements.

As shown above, the diverse arrangement of carbon, hydrogen, and oxygen can yield a myriad of structures, which open the door for distinct functions. The table below contains representative set of functions for lipids.

Lipids
The table above represents a few characteristic functions of lipids.

Proteins

Proteins, which are composed of amino acids, are one of the most diverse biological macromolecules within a cell. It is composed of carbon (C), hydrogen (H), oxygen (O), nitrogen (N), and, occasionally, sulfur (S). The image below shows a linear form of a protein.

Protein
A schematic representing the primary structure of a protein.

The table below shows representative functions of proteins.

Proteins
The table above represents a few characteristic functions of proteins.

Nucleic Acids

Nucleic acids, which are composed of nucleotides, include both DNA and RNA. It is composed of carbon (C), hydrogen (H), oxygen (O), nitrogen (N), and phosphorus (P). The image below demonstrates the helical form of DNA and RNA.

Nucleic Acids
A schematic representing double-stranded DNA and single-stranded RNA.

The table below shows a representative set of functions.

The table above represents a few characteristic functions of nucleic acids.

Biological Macromolecules Practice Problems

Problem 1

A researcher is extracting an unknown macromolecule from a newly discovered species of bacteria and performs mass spectrometry (MS) to deduce the elemental composition. The spectra reveals the composition to be of carbon, hydrogen, oxygen, nitrogen, and phosphorus. Identify the macromolecule it most likely is.

Problem 2

Analysis of an invasive species of bird reveals that it contains glycogen. Identify the macromolecule which composes glycogen.

Problem 3

A student analyzes the outer mitochondrial membrane of a muscle cell in a mouse and determines it to contain 40%-50% cholesterol. Identify the macromolecule cholesterol belongs to.

Biological Macromolecules Practice Problem Solutions

Problem 1

It is most likely a nucleic acid, such as DNA or RNA.

Problem 2

The macromolecule is a carbohydrate.

Problem 3

The macromolecule is a lipid.

Further Reading

For further information, this article contains lots of information of nucleotides!